From Mud to Rocks

Agnes just gave us a nice primer on mud.  But what happens next to make mud into a rock?

First, we need to answer the question, What’s a rock? 

This is a simple question, but it’s tricky to tie down a simple AND satisfying answer.  Most of the geologists I asked on board said, “A rock is a solid aggregate of minerals.”  That’s what a textbook says, but others disagree with the boundaries of this definition.  What about coal?  That’s not made of minerals.  What about our bones?  They’re not rocks.

“Making boxes is difficult in a messy world,” sedimentologist Kitty Miliken told me when I asked her about the definition of a rock.  “If you’re going to be a scientist”, she said, you’ll want to make a lot of boxes.  “But you need to be prepared for Nature not to respect your boxes.”  So, according to Kitty, the boundaries of the box around “rock” are:
– naturally occurring
– hard
– solid
– that’s not easily disaggregated or broken apart
– not just made by a single organism, though it may contain parts of organisms (fossils)
– and is any combination of the following:
– an aggregate of minerals and/or organic material
– monocrystalline or polycrystalline
– all of one composition or a mixture of different compositions.

This seems to work for our purposes of what’s rock and what’s not yet a rock.  Note that some rocks do break apart easily.  Shale by definition breaks into sheet-like layers.  But it’s still a coherent mass of mineral grains that doesn’t just fall apart in your hands.

The sediments we’re looking at are well on their way to fitting this definition: they’re naturally occurring, the individual grains or minerals or fossils are hard (though the combination of them is not yet hard), they’re individually solid, and they’re not made just by one organism.  There are lots of different minerals, so in this case the rocks that our sediments will turn into are polycrystalline and a mixture of different compositions.  Some rocks are made of just one mineral, like quartzite (quartz) or limestone (calcite).

When sediments settle to the seafloor, they form a layer of particles, whether they’re grains of sand, silt, and clay from land or tiny micro-organisms that lived in the ocean.  Sediments are already made of the right stuff, but they might not yet be rocks. The young sediments in the upper kilometer or so of seafloor that we drilled through were not yet rocks.  For the first few hundred meters of the holes at Site U1480, the sediments were soft and easily disaggregated.  That is, we could easily take a tiny toothpick scoop of sand or mud and smear it around on a smear slide, as Agnes explained in a recent blog post.

What exactly the sediments are made of determines how quickly they’ll become a true rock.  Carbonate minerals eventually make up rocks like limestone. They’re reactive and can quickly turn into rock.  If you go to the beach in the Caribbean, where there are high concentrations of carbonate minerals in the seawater, you can see rocks forming over a time period of years.  It can take millions or even tens of millions of years for sand and mud to turn to rock.  This process of becoming a rock can be sped up if there’s carbonate-rich water flowing between the grains of sand and mud or carbonate grains (shell fragments, calcareous algae flakes, etc.).  The calcium, carbon, oxygen, and other atoms that make up carbonate minerals dissolved in the water can then grow together as carbonate minerals between grains of sediment and glue them together.  This is called cementation.  Carbonate minerals can also glue non-carbonate chunks together.  We found a layer of proper sandstone in one of our cores, with carbonate minerals cementing the sand grains together.

 

 

The image shows a core section scan with close-up photos taken with a microscope, looking through a very thin slice of the rock glued to a glass slide.

There were layers of unconsolidated sand above and below that were not yet sandstone because the grains weren’t cemented together.  We interpret that this rock layer must have been a place where underground water could flow because sand is very porous and permeable, meaning water can easily flow through it.  The water was rich in carbonate ingredients, so carbonate minerals were able to glue the grains of sand together.  Other kinds of cement are silica and iron oxide.  The iconic red sandstones of the American Southwest owe their color to iron oxide cement. The grains of sand that comprise them are actually mostly colorless quartz!

 

Sandstones with iron oxide cement in Arches National Park, Utah.  (Photo © Naomi Barshi)

In addition to cementation, compaction also helps turn loose sediments into rocks.  As sediments get buried by more sediments and water above, they “feel” more and more pressure.  Even just 4200 m of water, where we are now, provides 400 times as much pressure as the atmosphere exerts on us. At 1000 mbsf, there’s an additional 200 times atmospheric pressure just from the overlying sediments.  We could very clearly see the difference between young, uncompacted sediments at the top of the hole and much older (more than 60 million years older!) compacted sediments and true sedimentary rocks near the base of the hole.  Here are some photos for comparison.  The first is some silty, clayey land-derived sediment very characteristic of the mid-shallow subsurface of the ocean.

Compaction by increased pressure, increasing temperature with depth, and the flow of fluids in the spaces between the rocks can also change the chemical composition of the sediments.  Minerals can have many different elements inside their crystal lattice structures, including hydrogen and oxygen together as hydroxide.  These can be squeezed or heated off.  The oxygen and hydrogen they combine into to pure water plus a new, chemically dry mineral left behind.  These kinds of mineral reactions are called “dehydration reactions” and are very important for the behavior of rocks and sediments, especially when they get hot and are put under pressure.  Water weakens rocks and sediments, lets rocks melt at lower temperatures, and makes sediments more slippery.  We can tell if these reactions are happening in the sediments by measuring the composition of interstitial water in the cores.  We squeeze the water out of the sediments in the chemistry lab (physically only—we don’t squeeze so hard that we cause chemical de-watering).  We expect that the interstitial water should be seawater, so if we see freshwater, we know it’s from dehydration reactions.  Water moving between the grains of sediments and rocks can also react with the minerals to form new, chemically wet minerals.  This can cause changes in volume and has all sorts of implications for rock composition and strength.  Lest I write a geology textbook instead of a blog post, I’ll cut this discussion short here.  (Email me or send us a Facebook<  message if you want to know more about the effect of water on rock behavior at elevated temperatures and pressures.  You’ll find my email in my blogger profile.)

Once the sediments are cemented together, possibly including compaction, they are no longer easy to break apart.  They’re now hard and solid on a larger scale, not just individual hard and solid particles.  This process of sediments turning into rocks is called lithification.  “Lithos” means “rock” in Greek.  Keep an eye out for that word root!  Lithology, lithography, monolith, lithic fragments…

There are of course other ways of making rocks, but we’ll leave igneous and metamorphic rocks for another time.