Oxygen Isotopes as a Proxy

A proxy is an indicator for something. For example, the density of  a sediment core could be a proxy for porosity. Isotopes are atoms of the same element with differing number of neutrons. There are three isotopes of oxygen. 16O and 18O are present in the air and the oceans.

The ratio of 18O to 16O gives us an estimate of what the ocean water was like through time. Organisms that build their tests from ions in ocean water record the amount of 18O and 16O that was present during their life cycle. The ratio of 18O to 16O in the tests of ocean organisms acts as a proxy for ice volume. How? 16O preferentially evaporates because it is the lighter of the two isotopes. Since it's easier to evaporate the smaller isotopes, rain/snow are high in 16O. This would make glaciers 16O - rich too. Given the aforementioned facts, ocean water is higher in 18O during glacial periods, and one would also expect ice volume to be greater when 18O values are higher in ocean water and ocean organisms that build their tests from the water. The ratio in the critters also acts as a proxy for ice volume.

On an unrelated note, sunset was stunning this evening. I could tell the ship had gained some latitude because sunrise was after 21:00 tonight!  I walked out on the deck at the perfect time to see the sunset, a gorgeous glitter path AND crepuscular rays! Some of my shipmates beat me to it. I think that everyone got a chance to look.

Comments

Climate change proxies

Thanks for this blog entry, Heather! I'm going to send my teachers to it - the folks bravely taking earth science from me at Penn! God help them all! :) Hope you are having a wonderful time!
Mike

Penn

Hi, Mike.

I saw on FB that you are having a great time with your class. No surprise! Thanks for following along, Mike. I have a better understanding of most geologic concepts, and I better understand all of the samples I processed while working at IUP.

HEATHER !

Thank you for sharing the pictures and experiences of your voyage - Michelle Gross - Jefferson, NH

Thanks!

Hi, Michelle!

Thanks for reading! We miss you at WMRHS!

O-16/18

Hi Heather. Thanks for sharing!! And now, according to Z. Huang, Science News, 6/20/09, pg14, the O-16/18 ratio in plant produced silica varies with temperature so that if the silica data is used along with carbon-dating, it could provide Earth climate data for up to 300,000 years ago. Ocean cores and this silica data may help us understand past climate changes. I suppose the test for 0-18/16 requires an expensive instrument.... Jackie

Isotopes

Hi, Jackie!

Thanks for that. Interesting that you mention silicon because yesterday we talked about how a scientist from CalTech is actually trying to measure helium in the sediments - HELIUM! How about that? One of our instructors who has acted as IOPD curator (and has seen all requests that scientists send for sampling and research) mentioned that it seems we are heading down a path where we will be able to use any element that has isotopes for proxy purposes (we just need to find out what their ratios and presence indicate!). Cool, eh?